Kinetics of Oxidation of Schiff Base by Chloramine –T Catalysed by Mixture of Os (Viii) and Ru (Iii) – Effect of Osmium Tetraoxide and Ruthenium Chloride

 
 
International Journal of Biotech Trends and Technology (IJBTT)
 
© 2012 by IJBTT Journal
Volume - 2 Issue - 1                          
Year of Publication : 2012
Authors :G.Mathubala 1 , Dr.V.Krishnasamy

Citation

G.Mathubala, Dr.V.Krishnasamy "Kinetics of Oxidation of Schiff Base by Chloramine –T Catalysed by Mixture of Os (Viii) and Ru (Iii) – Effect of Osmium Tetraoxide and Ruthenium Chloride",International Journal of Biotech Trends and Technology (IJBTT), V2(1):4-10 Jan - Mar 2012. Published by Seventh Sense Research Group.

Abstract

The kinetic study of simple and substituted anils ware studied under various conditions viz., solvent ,oxidants , electrolyte , catalysts and mixture of catalysts and temperature; simple and substituted anils , pyridinium Chloro Chromate(PCC) ,Pyridinium Dichromate ( PDC) were prepared in the laboratory and kinetic study were carried out using Pyridinium dichromate , substrate , perchloric acid and osmium tetraoxide . The graphs were drawn at all relevant places and results were obtained in full satisfaction.

References

1.S.P.Mushram , M.G.Agarwal and B.Prasad , J. Chem. Soc. Sect.B 1971 , 1712
2. M.C.Agarwal ,S.P.Mushram , J. Phys . Chem .75 838 , 1971
3. P.S.Radhakrishnamurthi and B.Sahu , Indian J.Chem. 1978 , 16A , 25
4.Vivekanandan ,K.Venkata Rao , M.Sakappa and SP.Shanmuganathan , Indian J.Chem. 16 A , 595 , 1978
5.J.Hussain ,S.K.Mishra and P.D.Sharma , J. Chem. Soc., Dalton Trans , 89 , 1991
6.C.K.Mythily , K.S.Rangappa and D.S.Mahadevappa , Indian J.Chem . 1990 , 29A , 676.

Keywords
diverse nature , chloramine [CAT], sulphonamide , oxidants , water – bath , evaporating , stirring.