Kinetic study of Oxidation of n-methyl - 2,6-diphynyl – piperidin-4-one Oxime [NMPO] - effect of varying sodium Per chlorate effect of ionic strength(NaClO4) - 94 %

Kinetic study of Oxidation of n-methyl - 2,6-diphynyl – piperidin-4-one Oxime [NMPO] - effect of varying sodium Per chlorate effect of ionic strength(NaClO4) - 94 %

 
 		 International Journal of Biotech Trends and Technology (IJBTT)
 
© 2016 by IJBTT Journal
Volume - 6 Issue - 2                         
Year of Publication : 2016
Authors : R.Kalpana Devi, G.Mathubala

Citation

R.Kalpana Devi, G.Mathubala "Kinetic study of Oxidation of n-methyl - 2,6-diphynyl – piperidin-4-one Oxime [NMPO] - effect of varying sodium Per chlorate effect of ionic strength(NaClO4) - 94 %", International Journal of Biotech Trends and Technology (IJBTT), V6(2): 18-22 Apr - Jun 2016, Published by Seventh Sense Research Group.

Abstract

PCC and N-methyl -2,6-diphynyl – piperidin-4-One Oxime were prepared , PCC by the method of Corey and Suggs. Then acetic acid was purified. Other reagents such asAnalar samples of Sodium Perchlorate and Trichloroacetic acid was used as such. Doubly distilled water was used throughout. The purity of PCC was checked by estimating Cr(IV) iodometrically . The reaction was done at constant temperature (± 0.10 C) and was followed iodometrically. The liberalized iodine was titrated against standardized sodium thiosulphate . The titration was repeated for the subsequent intervals of time The first order rate constant was found from the slope of the log litre plots by least square method. First kinetic study of oxidation of Nmethyl -2,6-diphynyl – piperidin-4-one oxime [NMPO] - by varying the concentration of the Sodium Perchlorate . (NaClO4).

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Keywords
N-methyl -2,6-diphynyl – piperidin-4-one oxime ,Kinetic study ,oxidant , rate constant , slope , least square method.